WebNov 8, 2000 · Synthesis of Cavity Extended Cyclotriveratrylenes. The Journal of Organic Chemistry 2004 , 69 (4) , 1386-1388. DOI: 10.1021/jo035557m. WebMar 31, 2024 · A fluorescent cage receptor for the detection of choline in pseudophysiological medium that is selective toward acetylcholine and also selective toward choline with an association constant greater than 9.9 × 104 M-1 in buffered medium is described. A fluorescent cage receptor for the detection of choline in …
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WebAromatic nucleophilic substitution reaction of cyclotriguaiacylene 1 with fluorobenzene derivatives bearing electron-withdrawing groups X (CHO, COCH 3, CN, NO 2) in the para position gives a series of cyclotriveratrylene derivatives ( 3a−d ), where the X substituents can be transformed to hydrogen-bond donor groups to afford new CTV-based … Cyclotriveratrylene (CTV) is an organic compound with the formula [C6H2(OCH3)2CH2]3. It is a white solid that is soluble in organic solvents. The compound is a macrocycle and used in host–guest chemistry as a molecular host. See more The compound can be synthesised from veratrole alcohol upon acid catalysis. Operating via the same intermediates, an alternative synthesis involves the acid-catalyzed reaction of veratrole and formaldehyde. … See more CTV has a bowl shaped conformation, giving the molecule C3 symmetry. The ether groups are situated at the upper rim, but in contrast a crown ether typically do not interact with guests. The compound is related to calixarenes in terms of its host–guest … See more CTV was first synthesised by Gertrude Robinson in 1915 but misdiagnosed as the dimer. In 1965, Lindsey identified the correct structure and coined cyclotriveratrylene … See more how many quarters equals one loonie
Controlled Access to C1‐Symmetrical Cyclotriveratrylenes (CTVs) …
WebFeb 18, 2012 · Cyclotriveratrylenes 1 represent an important class of molecular receptors, especially as their rigid crown conformation favours spherical guests, such … WebOct 20, 2015 · A series of C 3 ‐symmetric triiodocyclotriveratrylene (CTV‐I 3) derivatives have been successfully arylated to afford the corresponding … WebJul 1, 2024 · We describe here a controlled approach to C1 -symmetrical cyclotriveratrylenes (CTVs). In this approach dimers are synthesized through … how data warehouse and web related